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Thermionic emission is the thermally induced flow of charge carriers from a surface or over a potential-energy barrier. This occurs because the thermal energy given to the carrier overcomes the work function of the material. The charge carriers can be electrons or ions, and in older literature are sometimes referred to as "thermions". After emission, a charge that is equal in magnitude and opposite in sign to the total charge emitted is initially left behind in the emitting region. But if the emitter is connected to a battery, the charge left behind is neutralized by charge supplied by the battery as the emitted charge carriers move away from the emitter, and finally the emitter will be in the same state as it was before emission. The classical example of thermionic emission is the emission of electrons from a hot cathode into a vacuum (also known as thermal electron emission or the Edison effect) in a vacuum tube. The hot cathode can be a metal filament, a coated metal filament, or a separate structure of metal or carbides or borides of transition metals. Vacuum emission from metals tends to become significant only for temperatures over . The science dealing with this phenomenon has been known as "thermionics", but this name seems to be gradually falling into disuse. The term "thermionic emission" is now also used to refer to any thermally-excited charge emission process, even when the charge is emitted from one solid-state region into another. This process is crucially important in the operation of a variety of electronic devices and can be used for electricity generation (such as thermionic converters and electrodynamic tethers) or cooling. The magnitude of the charge flow increases dramatically with increasing temperature. ==History== Because the electron was not identified as a separate physical particle until the 1897 work of J. J. Thomson, the word "electron" was not used when discussing experiments that took place before this date. The phenomenon was initially reported in 1873 by Frederick Guthrie in Britain.〔See: * *〕 While doing work on charged objects, Guthrie discovered that a red-hot iron sphere with a negative charge would lose its charge (by somehow discharging it into air). He also found that this did not happen if the sphere had a positive charge.〔 〕 Other early contributors included Johann Wilhelm Hittorf (1869–1883),〔See: * * * * * *〕 Eugen Goldstein (1885),〔E. Goldstein (1885) ("Ueber electrische Leitung in Vacuum" ) (On electric conduction in vacuum) ''Annalen der Physik und Chemie'', 3rd series, 24 : 79-92.〕 and Julius Elster and Hans Friedrich Geitel (1882–1889).〔See: * Elster and Geitel (1882) ("Ueber die Electricität der Flamme" ) (On the electricity of flames), ''Annalen der Physik und Chemie'', 3rd series, 16 : 193-222. * Elster and Geitel (1883) ("Ueber Electricitätserregung beim Contact von Gasen und glühenden Körpern" ) (On the generation of electricity by the contact of gases and incandescent bodies), ''Annalen der Physik und Chemie'', 3rd series, 19 : 588-624. * Elster and Geitel (1885) ("Ueber die unipolare Leitung erhitzter Gase" ) (On the unipolar conductivity of heated gases") ''Annalen der Physik und Chemie'', 3rd series, 26 : 1-9. * Elster and Geitel (1887) ("Ueber die Electrisirung der Gase durch glühende Körper" ) (On the electrification of gases by incandescent bodies") ''Annalen der Physik und Chemie'', 3rd series, 31 : 109-127. * Elster and Geitel (1889) ("Ueber die Electricitätserregung beim Contact verdünnter Gase mit galvanisch glühenden Drähten" ) (On the generation of electricity by contact of rarefied gas with electrically heated wires) ''Annalen der Physik und Chemie'', 3rd series, 37 : 315-329.〕 The effect was rediscovered by Thomas Edison on February 13, 1880, while trying to discover the reason for breakage of lamp filaments and uneven blackening (darkest near the positive terminal of the filament) of the bulbs in his incandescent lamps. Edison built several experimental lamp bulbs with an extra wire, metal plate, or foil inside the bulb that was separate from the filament and thus could serve as an electrode. He connected a galvanometer, a device used to measure current (the flow of charge), to the output of the extra metal electrode. If the foil was put at a negative potential relative to the filament, there was no measurable current between the filament and the foil. When the foil was raised to a positive potential relative to the filament, there could be a significant current between the filament through the vacuum to the foil if the filament was heated sufficiently (by its own external power source). We now know that the filament was emitting electrons, which were attracted to a positively charged foil, but not a negatively charged one. This one-way current was called the ''Edison effect'' (although the term is occasionally used to refer to thermionic emission itself). He found that the current emitted by the hot filament increased rapidly with increasing voltage, and filed a patent application for a voltage-regulating device using the effect on November 15, 1883 (U.S. patent 307,031, the first US patent for an electronic device). He found that sufficient current would pass through the device to operate a telegraph sounder. This was exhibited at the International Electrical Exposition in Philadelphia in September 1884. William Preece, a British scientist, took back with him several of the Edison effect bulbs. He presented a paper on them in 1885, where he referred to thermionic emission as the "Edison Effect."〔 Preece coins the term the "Edison effect" on page 229.〕〔 〕 The British physicist John Ambrose Fleming, working for the British "Wireless Telegraphy" Company, discovered that the Edison Effect could be used to detect radio waves. Fleming went on to develop the two-element vacuum tube known as the diode, which he patented on November 16, 1904.〔See: * Provisional specification for a thermionic valve was lodged on November 16, 1904. In this document, Fleming coined the British term "valve" for what in North America is called a "vacuum tube": "The means I employ for this purpose consists in the insertion in the circuit of the alternating current of an appliance which permits only the passage of electric current in one direction and constitutes therefore an electrical valve." * *〕 The thermionic diode can also be configured as a device that converts a heat difference to electric power directly without moving parts (a thermionic converter, a type of heat engine). ==Richardson's Law== Following J. J. Thomson's identification of the electron in 1897, the British physicist Owen Willans Richardson began work on the topic that he later called "thermionic emission". He received a Nobel Prize in Physics in 1928 "for his work on the thermionic phenomenon and especially for the discovery of the law named after him". From band theory, there are one or two electrons per atom in a solid that are free to move from atom to atom. This is sometimes collectively referred to as a "sea of electrons". Their velocities follow a statistical distribution, rather than being uniform, and occasionally an electron will have enough velocity to exit the metal without being pulled back in. The minimum amount of energy needed for an electron to leave a surface is called the work function. The work function is characteristic of the material and for most metals is on the order of several electronvolts. Thermionic currents can be increased by decreasing the work function. This often-desired goal can be achieved by applying various oxide coatings to the wire. In 1901 Richardson published the results of his experiments: the current from a heated wire seemed to depend exponentially on the temperature of the wire with a mathematical form similar to the Arrhenius equation.〔O. W. Richardson (1901) ("On the negative radiation from hot platinum," ) ''Philosophical of the Cambridge Philosophical Society'', 11 : 286-295.〕 Later, he proposed that the emission law should have the mathematical form 〔 : where ''J'' is the emission current density, ''T'' is the temperature of the metal, ''W'' is the work function of the metal, ''k'' is the Boltzmann constant, and ''A''G is a parameter discussed next. In the period 1911 to 1930, as physical understanding of the behaviour of electrons in metals increased, various theoretical expressions (based on different physical assumptions) were put forwards for ''A''G, by Richardson, Saul Dushman, Ralph H. Fowler, Arnold Sommerfeld and Lothar Wolfgang Nordheim. Over 60 years later, there is still no consensus amongst interested theoreticians as to what is the exact expression of ''A''G, but there is agreement that ''A''G must be written in the form : where ''λ''R is a material-specific correction factor that is typically of order 0.5, and ''A''0 is a universal constant given by 〔 〕 : where ''m'' and −''e'' are the mass and charge of an electron, and ''h'' is Planck's constant. In fact, by about 1930 there was agreement that, due to the wave-like nature of electrons, some proportion ''r''av of the outgoing electrons would be reflected as they reached the emitter surface, so the emission current density would be reduced, and ''λ''R would have the value (1-''r''av). Thus, one sometimes sees the thermionic emission equation written in the form :. However, a modern theoretical treatment by Modinos assumes that the band-structure of the emitting material must also be taken into account. This would introduce a second correction factor ''λ''B into ''λ''R, giving . Experimental values for the "generalized" coefficient ''A''G are generally of the order of magnitude of ''A''0, but do differ significantly as between different emitting materials, and can differ as between different crystallographic faces of the same material. At least qualitatively, these experimental differences can be explained as due to differences in the value of ''λ''R. Considerable confusion exists in the literature of this area because: (1) many sources do not distinguish between ''A''G and ''A''0, but just use the symbol ''A'' (and sometimes the name "Richardson constant") indiscriminately; (2) equations with and without the correction factor here denoted by ''λ''R are both given the same name; and (3) a variety of names exist for these equations, including "Richardson equation", "Dushman's equation", "Richardson–Dushman equation" and "Richardson–Laue–Dushman equation". In the literature, the elementary equation is sometimes given in circumstances where the generalized equation would be more appropriate, and this in itself can cause confusion. To avoid misunderstandings, the meaning of any "A-like" symbol should always be explicitly defined in terms of the more fundamental quantities involved. Because of the exponential function, the current increases rapidly with temperature when ''kT'' is less than ''W''. (For essentially every material, melting occurs well before ''kT'' = ''W''.) 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Thermionic emission」の詳細全文を読む スポンサード リンク
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